Outline
DOI: 10.1039/d6dt01945e ISSN: 1477-9226
Field-induced single-molecule magnetism in aminyl radical-bridged trinuclear lanthanide clusters
Dan Liu, Changjiang Wu, Qiang Liu, Huayi Fang, Yin-Shan MengA series of isostructural trinuclear lanthanide complexes (1-Ln) bridged by aminyl radicals (–NH˙ − ) were synthesized. Both 1-Dy and 1-Er behave solely as field-induced SMMs, with their relaxation processes following the Orbach mechanism.
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