Enhancing Birefringence of Sulphates by Polarity Modification in Planar Cations
Bohui Xu, Pifu Gong, Deshuai Xiao, Linfeng Dong, Xiaodong Zhang, Qian Huang, Zhu Siya, Xinyuan Zhang, Zheshuai LinABSTRACT
Sulphates are regarded as important optical materials owing to their broad transparency, yet their application is limited by weak birefringence from highly symmetric [SO 4 ] units. Herein, we enhance the birefringence in sulphates via cation polarity modification by introducing 1,1‐dimethylguanidinium ([C 3 N 3 H 12 ] + , GC 2 + ), which shows twofold higher polarizability anisotropy than the parent planar guanidinium ([CN 3 H 6 ] + , or G + ). High‐quality C 3 N 3 H 12 HSO 4 crystals grown from a facile and safe aqueous route exhibit a large birefringence of 0.105 @ 546 nm, 73% higher than that of the guanidine‐based [CN 3 H 6 ]HSO 4 . First‐principles calculations confirm that GC 2 + not only boosts polarizability anisotropy but also promotes the oriented alignment of [SO 4 ] units via an extensive hydrogen‐bonding network, leading to optimal structural ordering. This work highlights a synergistic strategy using polar cations and hydrogen‐bond‐directed assembly to design high‐performance birefringent materials.