DOI: 10.1039/d6py00673f ISSN: 1759-9954
Embedding diazirine-based carbene precursors into polyolefins via catalyst-tuned olefin metathesis
Hong-Gyu Seong, Mizhi Xu, Haley K. Beech, Youngbum Lee, Kazuhisa Iwaso, Craig J. HawkerCatalyst selection enables direct ROMP incorporation of diazirines into polyolefin backbones while preserving their reactivity, providing efficient macromolecular crosslinkers for hydrocarbon polymers.