Electrochemically Induced Regio‐ and Stereoselective ( E )‐β‐C(sp ² )─H Alkoxycarbonylation of Enamides With Carbazates

Herein, we disclosed an electrochemically induced alkoxycarbonylation of enamides with carbazates under metal‐free and peroxide‐free reaction conditions, which provided a green protocol for constructing enol esters, exhibiting excellent regioselectivity and mainly affording products in the E ‐configuration. Mechanistically, a free alkoxycarbonyl radical pathway was involved in this approach.