DOI: 10.1039/d6dt01600f ISSN: 1477-9226

Electrochemical CO 2 reduction by phosphine-modified [FeFe]-hydrogenase models

Guilherme L. Tripodi, Lucile Chatelain, Bas J. Klement, Antoine Bulourde, Carole Duboc, Noémie Lalaoui

A series of phosphine-substituted [FeFe]-hydrogenase model complexes was synthesized and investigated for electrocatalytic CO 2 reduction, revealing selective formate production and ligand-dependent reactivity.