Effect of Silver Content and T4 Treatment on the In Vitro Degradation Behavior of Gasar Porous Mg–Ag Alloy

Mg–Ag alloy has potential as a material for bone tissue repair, but the faster degradation rate in vivo limits its use in medical applications. In this study, pure Mg and Mg_99.5Ag_0.5 alloy with a porous structure are prepared using the metal/gas eutectic unidirectional solidification method (Gasar process). The influence of introducing Ag on the degradation behavior of porous Mg_99.5Ag_0.5 and pure Mg is investigated. The addition of Ag increases the compressive strength and elastic modulus of the material. The corrosion resistance of as‐cast Mg_99.5Ag_0.5 alloy decreases due to localized aggregation of Ag in the alloys. Therefore, the T4 (solution treatment) is chosen for the Mg_99.5Ag_0.5 alloy. After T4 treatment, due to the uniform distribution of Ag atoms in the alloy, the corrosion behavior on the alloy surface is more uniform, and a denser Mg(OH)₂ passivation layer is formed on the surface, which reduces the degradation rate of Mg_99.5Ag_0.5. Importantly, insoluble Ca–P compounds in the form of hydroxyapatite (HA) phases gradually grown on passivated layers of porous T4 Mg_99.5Ag_0.5 contribute to bone growth. This indicates the feasibility of using the T4 Gasar porous Mg_99.5Ag_0.5 alloy as a potential tissue engineering scaffold.