Effect of NASCION‐Type ceramic dispersion in PAN/PVA‐based blend polymer electrolyte: A structural, thermal, and electrical study

Abstract

Solid flexible separators having adequate ion conductivity at ambient temperature along with good thermal and voltage stability are potential candidates for separators in all solid‐state ion batteries. In the present work, zirconium and niobium‐doped Li_1.3Al_0.3Ti_1.7 (PO₄)₃ ceramic particles have been incorporated into a polyvinyl alcohol (PVA) and polyacrylonitrile (PAN)‐based blend that served as a flexible matrix to create a flexible polymer–ceramic framework and have been examined for conductivity, dielectric properties, voltage stability, thermal stability, and electrochemical performance. The flexible polymer–ceramic framework shows high thermal stability, improved conductivity, and a high‐voltage window. Optimized dc conductivity of 9.8 × 10⁻⁵ S cm⁻¹ has been observed among all investigated samples, with an improved voltage stability of 4.94 V. Further, the Trukhan model has been used to understand the effect of filler loading on ion migration properties. The optimized solid polymer electrolyte (SPE) shows improved ion mobility (μ) of 5.13 × 10⁻² cm² V⁻¹ s, number density (n) = 2.39 × 10¹⁵ cm³, and diffusion coefficient (D) of 2.09 × 10⁻³ cm² s⁻¹. It also shows a very high specific capacitance of ~10⁻⁴ Fg⁻¹, excellent cycling stability, and 93.75% capacity retention after 100 cycles.