Effect of Microalloying Elements on the Microstructure and Elevated-Temperature Mechanical Behavior of High-Strength Drill Pipe Steel

The mechanical behavior of S135 and V150 (Mo-V-Nb microalloyed) drill pipe steels was systematically investigated at room temperature (RT) and elevated temperatures (100–300 °C), alongside the microstructural evolution after long-term thermal exposure at 310 °C (200–500 h). V150 steel exhibits a superior RT yield strength (1099 vs. 1012 MPa) relative to S135, attributed to grain refinement and precipitation strengthening from nanoscale MC precipitates. However, at 200–300 °C, S135 steel displays strength recovery due to dynamic strain aging (DSA) facilitated by the formation of Cottrell atmospheres. Conversely, in V150 steel, V and Nb pin free interstitial atoms, suppressing Cottrell atmosphere formation and DSA. Consequently, V150 cannot gain DSA-induced strengthening, resulting in a steeper yield strength decline (a 17.3% drop at 300 °C versus 11.5% for S135). Long-term thermal exposure further reveals divergent microstructural evolution: S135 steel achieves synchronous improvements in strength and ductility via the transformation of coarse M3C into stable alloy carbides and the precipitation of nanoscale Mo-enriched carbides. In contrast, V150 steel undergoes Ostwald ripening and coherency loss of high-volume-fraction nano-MC precipitates, weakening dislocation pinning and accelerating dislocation annihilation, ultimately leading to the simultaneous degradation of strength and ductility. This study elucidates that while Mo-V-Nb microalloying enhances RT strength, it compromises high-temperature mechanical stability.