Effect of High Temperatures on Fire-Retardant-Modified Spruce and Beech Wood: Thermal Analysis, Heat Transfer, Chemical Composition, and Physical Properties

Potassium silicate is used as an inorganic fire-retardant treatment for wood, but its effect on the short-term thermal response of different species under combined temperature–moisture conditions remains insufficiently described. This study investigated spruce (Picea abies (L.) H. Karst) and beech (Fagus sylvatica L.) wood impregnated with potassium silicate and exposed to temperatures representing drying, mild thermal loading and the onset of thermal degradation. The evaluation included impregnation uptake, moisture content, mass changes, heat-transfer behavior, differential scanning calorimetry (DSC), chemical composition, Fourier-transform infrared spectroscopy (FTIR) of isolated cellulose and color measurements. Spruce showed higher uptake than beech, with an average weight percentage gain (WPG) of 10.5% compared with 3.6%. The treatment increased equilibrium moisture content by 2.6 percentage points in spruce and 1.1 percentage points in beech. Heat-transfer measurements showed that temperature and moisture governed heating: higher target temperatures were reached faster, whereas air-conditioned samples heated more slowly due to water evaporation. At lower temperatures, the direct effect of impregnation on heating time was limited, whereas at higher temperatures the treatment more clearly affected the subsequent degradation response. DSC revealed lower thermal resistance of beech and increased endothermic heat absorption in impregnated samples, particularly spruce. Higher-temperature exposure caused mass loss, hemicellulose degradation, moderate cellulose structure modification and visible color changes, with ΔE* exceeding 52 in impregnated spruce after 210 °C. The elevated-temperature response was governed by wood species, uptake, moisture content and thermal exposure level.