Effect of Arctic Service Conditions on the Mechanical Properties and Damage Behavior of Glass Fiber and Carbon/Glass Hybrid-Reinforced Vinyl Ester Composites for Marine Applications

Glass fiber-reinforced polymer (GFRP) and carbon/glass hybrid fiber-reinforced polymer (HFRP) laminates with two vinyl ester resin systems were investigated to evaluate their early environmental response, residual mechanical performance, and damage behavior after moisture-assisted low-temperature exposure and freeze–thaw cycling (FTC). After 150 days of moisture preconditioning, the conditioned specimens were exposed to −50 °C or subjected to FTC between −50 °C and 22 °C. Tensile, compressive, flexural, in-plane shear, interlaminar shear, and compression-after-impact (CAI) tests were conducted. Fourier transform infrared spectroscopy (FTIR), dynamic mechanical analysis (DMA), and scanning electron microscopy (SEM) were used to examine chemical structure, thermomechanical response, and damage morphology. FTIR spectra showed no obvious changes in the characteristic absorption bands of the vinyl ester matrix. DMA showed condition-dependent changes in thermomechanical behavior, with the largest decrease in glass transition temperature reaching 5.5 °C after Condition 3. Tensile and in-plane shear properties were largely retained, whereas compressive, flexural, interlaminar shear, and CAI properties were more sensitive; the largest CAI strength loss was 19.1%. Hybrid stacking affected the property retention and damage tolerance of the laminates under the designed FTC condition. SEM observations identified interfacial debonding, matrix microcracking, and interlaminar crack growth as the main damage features.