Economic and Environmental Framework of Producing Green Hydrogen from Groundwater in South Africa: A Systematic Review

The hydrogen economy has emerged as a promising pathway to address climate change and ensure long-term global energy security, with water electrolysis powered by renewable energy as a key enabler of sustainable hydrogen production. Recent advances in various electrolyser technologies have enhanced their suitability for industrial applications, creating new opportunities for deploying green hydrogen. To address the gap in integrated, multi-dimensional assessment tools for groundwater-based hydrogen systems in water-scarce developing countries, this study develops and presents a Structured Assessment Framework for Green Hydrogen Production from Groundwater in South Africa—the first framework to simultaneously integrate hydrogeological sustainability screening, electrolyser technology selection under groundwater quality constraints, disaggregated levelised cost of hydrogen (LCOH) analysis including water treatment costs, comparative life cycle assessment (LCA) of green, blue, and grey hydrogen pathways, and policy and governance alignment within a single operationalised architecture. This included integrating five thematic dimensions: groundwater resource assessment, electrolyser technology integration, economic viability, environmental sustainability, and policy and governance considerations. This systematic review was conducted in accordance with the PRISMA 2020 guidelines, drawing on 130 studies retrieved from Scopus and Web of Science (2015–2025). The analysis examines groundwater quality and suitability, the technical feasibility of electrolyser systems, and the comparative implications of grey, blue, and green hydrogen pathways on cost and environmental performance. The framework also provides strategic guidance for deploying renewable-energy-powered hydrogen systems, emphasising life-cycle impacts, regulatory alignment, and the potential for decentralised hydrogen hubs. Findings highlight the significance of strengths, weaknesses, opportunities, and threats (SWOT) for green hydrogen production using groundwater in South Africa, including export potential and strong linkages to the circular economy. The study offers actionable insights for policymakers, planners, and industry stakeholders seeking to advance a sustainable and economically competitive hydrogen landscape.