DOI: 10.1039/d6cc05661j ISSN: 1359-7345
Divergent construction of Ni and Fe–Al–H assemblies
Jordan R. Gipper, Kritika Gour, Nattamai Bhuvanesh, Manar M. ShoshaniReaction of an Al-dihydride metalloligand with Ni(
ii
) and Fe(
ii
) halides affords heterotrimetallic hydrides featuring electron-rich transition-metal centers, with NiCl
2
undergoing reductive assembly and FeCl
2
hydride/halide metathesis.