DOI: 10.1039/d6dt01222a ISSN: 1477-9226

Distorted octahedral supramolecular cages based on spirobiindane with enhanced emission

Yijun Xiao, Zhantao Wang, Ning Wang, Fan Fu, Wanying Zhong, Zhengguang Li, Zhilong Jiang, Jun Wang, Pingshan Wang, Mingzhao Chen

By employing a C 2 -symmetric spirobiindane core, two distorted octahedral cages (S1 and S2) were successfully synthesized. Among them, S1 exhibited a high fluorescence quantum yield ( Φ F ) of up to 96.24% in 20% H 2 O/DMF.

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