DOI: 10.2298/sos260807009u ISSN: 0350-820X

Deposition of $ \mathrm{Gd_2O_3} $ coatings by detonation spraying

Vladimir Ulianitsky, Igor Batraev, Denis Rybin, Konstantin Kuper, Alexandr Shtertser, Boris Bokhonov, Olga Podgornova, Alexander Kalinkin, Dina Dudina, Eduard Pruuel, Ivan Rubtsov

\mathrm{Gd_2O_3} coatings were formed by detonation spraying for the first time. The coatings were sprayed using \mathrm{Gd_2O_3} and \mathrm{Gd_2O_2S} as feedstock powders. The spraying was conducted under oxidizing conditions using \mathrm{C_2H_2+2.5O_2} mixture. The \mathrm{Gd_2O_2S} transformed into \mathrm{Gd_2O_3} during spraying. Coatings 100 μm thick were formed on Al substrates. The velocities and temperatures of \mathrm{Gd_2O_3} particles accelerated in the barrel of the detonation gun were calculated. During spraying, the \mathrm{Gd_2O_3} particles experienced melting. Spraying of both feedstock powders resulted in the formation of monoclinic \mathrm{Gd_2O_3} . The coatings demonstrated luminescence when subjected to synchrotron radiation. The coating obtained from the \mathrm{Gd_2O_2S} feedstock powder demonstrated a higher intensity of luminescence than the coating obtained from the oxide. Aluminium plates coated with \mathrm{Gd_2O_3} derived from the oxide and \mathrm{Gd_2O_2S} feedstock powders were successfully employed as phosphor screens in the beam position monitor at the VEPP-3 synchrotron (Budker Institute of Nuclear Physics SB RAS).