DOI: 10.1039/d4cc06227b ISSN: 1359-7345

Coordination-induced axial chirality controls the metal-centred configuration in a stereogenic-at-iron catalyst

Benedikt Buchberger, Nemrud Demirel, Xiulan Xie, Sergei I. Ivlev, Eric Meggers

A new approach is introduced to control the metal-centred configuration of stereogenic-at-iron catalysts by utilizing axial ligand chirality, which becomes locked upon metal coordination.

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