Outline
DOI: 10.1039/d6gc04563d ISSN: 1463-9262
Consecutive electron and energy transfer photocatalysis enabled trifunctionalization of trifluoromethylalkenes
Mengyu Wu, Shiguan Wang, Chuan Zhu, Jian Zhang, Chao FengOne photocatalyst drives a consecutive SET/EnT cascade merging defluorinative alkylation and di-π-ethane rearrangement, enabling α,α-difluorobenzylcyclopropanes synthesis from trifluoromethylalkenes and carboxylic acids via C–F/C–C bond cleavage.
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