Catalytic Ozonation of Phenolic Wastewater Using MgO Nanocatalyst and Activated Carbon Honeycomb as Packing Material in the Bubble Column Reactor

Ozonation is one of the most widely used methods for wastewater treatment. However, it suffers from several drawbacks, including a low reaction rate, long reaction time, and the formation of intermediate byproducts due to incomplete oxidation. Therefore, in this paper, the ozonation process was improved via the MgO nanocatalyst and honeycomb activated carbon (HAC) as a packing material in the bubble column reactor by using the following methods: (O3/MgO, O3/HAC, and O3/MgO/HAC). The results showed that using ozone alone yielded a low chemical oxygen demand (COD) removal efficiency of 63.33% after 90 min, and the phenol concentration was 15 mg/L. However, when the catalyst was added, the efficiency increased to 73.33%, which is attributed to the enhanced generation of more hydroxyl radicals (OH•). The HAC packing material had a positive effect, as the removal efficiency rose to 76.66% due to its effective role in improving the mass transfer inside the reactor. The integrated (O3/MgO/HAC) method proved to be the most effective at achieving a COD removal efficiency of about 83%; furthermore, the efficiency reached 91% when the initial phenol concentration decreased to 10 mg/L. Two doses of catalysts were used, 0.05 and 0.1 g/L, and it was found that the higher dose (0.1 g/L) had the highest efficiency. The effect of the initial phenol concentration and ozone gas flow rate were studied. The study concludes that the use of the MgO nanocatalyst and the honeycomb-structured activated carbon packing material plays an effective role in improving the ozonation process by increasing the reaction rate, reducing treatment time, and decreasing the demand for additional ozone gas supplies, thus achieving significant economic benefits.