Outline
DOI: 10.1039/d6nj03590f ISSN: 1144-0546
Bulkier ligands, faster catalysts: chemical potential rather than steric bulk governs transfer hydrogenation by Cu(
ii
)-bzimpy complexes
Salih Günnaz Across eight Cu(
ii
)–bzimpy catalysts, transfer hydrogenation activity tracks the chemical potential of the complex (
r
² = 0.966) and not its buried volume: bulky wingtips act electronically, by raising electron density at copper.
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