DOI: 10.1002/pc.29481 ISSN: 0272-8397

Breakdown field strength and corona resistance of SiTiB/EP nanocomposites

Boxuan Wang, Hao Chen, Wei Zhao, Ling Weng, Minghao Sun, Jing Zhang, Shuang Yin, Mingyue Jiang, Chunping Wang, Xiangyu Shi

Abstract

This paper describes the process of designing and creating SiTiB nanocomposite oxides by utilizing phenyltriethoxysilane (PTES), tributyl borate, and butyl titanate as monomers. The SiTiB/EP nanocomposite was then created using ultrasonic dispersion and thermal curing. Investigation of the effects of different doping levels of SiTiB nanocomposite oxides on the dielectric properties, breakdown strength, corona resistance lifetime, volume resistivity, and electrical aging threshold of nanocomposites. The findings indicate that the introduction of SiTiB nanocomposite oxides in epoxy resins (EPs) does not result in the growth of the dielectric loss of the nanocomposites. With the rise in SiTiB nanocomposite oxide doping, the breakdown strength of SiTiB/EP nanocomposites exhibited a trend of initially augment and then decline, reaching a peak value of 289.2 kV/mm when the doping amount was 6 wt%. The corona‐resistant lifetime of SiTiB/EP nanocomposites exhibited a trend of initially augment and then decline with the rise of SiTiB nanocomposite oxide doping, and the maximum value of corona‐resistant lifetime was 311 min when the doping amount was 6 wt%, which was 5.03 times of the pure EP. The experimental results demonstrate that the incorporation of SiTiB nanocomposite oxides can enhance both the breakdown strength and corona‐resistant lifetime of the nanocomposites, without causing an increase in their dielectric loss.

Highlights

SiTiB composite oxides were designed and synthesized.

Analyzing the properties of SiTiB/EP composites with different doping levels.

SiTiB/EP composites have low dielectric loss.

SiTiB/EP composites have a longer corona‐resistance lifetime.

SiTiB/EP composites have high breakdown field strengths.

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