DOI: 10.1039/d6sc04846c ISSN: 2041-6520
Biasing the dynamic
Δ
/
Λ
equilibrium of a helical and luminescent Tb(
iii
) complex on chiral amine-func
Sora Shirai, Satoshi Muratsugu, Keiko Hibi, Naoki Yokoyama, Hisaki Matsui, Takafumi Shiraogawa, Masahiro Ehara, Hidetaka Nakai, Mizuki Tada A chiral 1-phenylethylamine-functionalized SiO 2 surface biases the Δ / Λ equilibrium of a racemic luminescent Tb(
iii
) (cyclen) complex and induces CD and CPL. Calculations suggest preferential
Δ
and
Λ
forms on the (
R
)- and (
S
)-surfaces, respectively.