DOI: 10.1002/ajoc.70577 ISSN: 2193-5807

Applications of TMSN 3 in Photo‐ and Electrocatalytic Organic Synthesis

Hong‐Tao Ji, Jin‐Feng Shang, Zi‐Ming Wang, Ji Zhou, Rong‐Qiang Li

ABSTRACT

Trimethylsilyl azide (TMSN 3 ) as a cheap and easily available azide/amine source is showing increasingly important applications in photocatalytic and electrochemical organic synthesis. This mini‐review systematically summarizes the latest applications of TMSN 3 in photocatalytic and electrocatalytic organic synthesis, and discusses the related mechanisms and development prospects.

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