Outline
DOI: 10.1039/d6dt02248k ISSN: 1477-9226
Allosteric reconstruction of copper(
i
) iodide dimers inside a metal–organic framework induced by adsorption of iodine
Joonsik Kim, Tomoyuki Umeyama, Yuki Wada, Colin J. Martin, Takaya Matsumoto, Pavel M. Usov, Masaki Kawano Copper(
i
) iodide framework featuring symmetric tetrahedral ligands enabled direct visualization of iodine sorption, including chemisorption, accompanied by reorientation of constituent dimeric Cu
2
I
2
units within a porous structure.
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