DOI: 10.1002/ejoc.202300719 ISSN:

Air‐Induced Hydroxyphosphorylation of α‐Trifluoromethyl Styrenes with H‐Phosphonates and H‐Phosphine Oxides

Jingjing He, Zhudi Sun, Yupian Deng, Ying Liu, Pai Zheng, Xuxue Zhang, Song Cao
  • Organic Chemistry
  • Physical and Theoretical Chemistry

Efficient synthesis of β‐hydroxy‐β‐CF3‐phosphonates and β‐hydroxy‐β‐CF3‐phosphine oxides via Mn‐mediated or transition‐metal‐free hydroxyphosphorylation of α‐(trifluoromethyl)styrenes with H‐phosphonates or H‐phosphine oxides with the assistance of air, respectively, was described.

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