DOI: 10.1039/d6qo01387b ISSN: 2052-4129
Additive-dependent carboxylate–carbonate coordination modulates Cu–C homolysis and radical termination in copper-catalyzed spirocyclization and alkene transposition: a DFT study
Yi Tang, Cui Lai, Abing DuanDFT calculations reveal that additive-dependent coordination and acid–base equilibria govern copper-catalyzed cyclization and alkene transposition.