DOI: 10.1039/d3dt02260a ISSN:
Acetate ion addition to and exchange in (1,5-cyclooctadiene)rhodium(i ) acetate: relevance for the coagulation of carboxylic acid-functionalized shells of core-crosslinked micelle latexes
Ambra Maria Fiore, Valentina Petrelli, Christophe Fliedel, Eric Manoury, Piero Mastrorilli, Rinaldo Poli - Inorganic Chemistry
[Rh(COD)(μ-OAc)]2 reacts with acetate in dichloromethane to produce equilibrium amounts of [Rh(COD)(OAc)2]− and exchanges the acetate ligands with polymer-linked methacrylic acid, rationalizing the coagulation of core-crosslinked micelle latexes.