DOI: 10.1039/d3dt02260a ISSN:

Acetate ion addition to and exchange in (1,5-cyclooctadiene)rhodium(i) acetate: relevance for the coagulation of carboxylic acid-functionalized shells of core-crosslinked micelle latexes

Ambra Maria Fiore, Valentina Petrelli, Christophe Fliedel, Eric Manoury, Piero Mastrorilli, Rinaldo Poli
  • Inorganic Chemistry

[Rh(COD)(μ-OAc)]2 reacts with acetate in dichloromethane to produce equilibrium amounts of [Rh(COD)(OAc)2] and exchanges the acetate ligands with polymer-linked methacrylic acid, rationalizing the coagulation of core-crosslinked micelle latexes.

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