DOI: 10.1039/d3dt01131c ISSN:
A tetracobalt(ii ) cluster with a two vertex truncated dicubane topology endogenously supported by carboxylate-based (2-pyridyl)methylamine ligands: magneto-structural and DFT studies
Shashi Kant, Sayan Saha, Francesc Lloret, Joan Cano, Rabindranath Mukherjee - Inorganic Chemistry
Detailed magneto-structural studies on a defective dicubane coordination cluster with structural core {CoII4Cl2(μ-1,1-OCO)4(μ3-OCH3)2} reveal two ferromagnetic and an antiferromagnetic exchange coupling, which is rationalized by DFT calculations.