DOI: 10.1039/d6dt02307j ISSN: 1477-9226

A super-bulky phosphanide ligand enables the observation of scalar coupling between 31 P and 7 Li, 23

Ahmed Hadadi, Corinne Y. Wills, Casey M. Dixon, Paul G. Waddell, Keith Izod

A full set of alkali metal complexes of a super-bulky phosphanide ligand was synthesised.  These compounds enable observation by NMR spectroscopy of scalar coupling between 31 P and heavier alkali metal nuclei for the first time.

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