Outline
DOI: 10.1021/acs.inorgchem.6c05115 ISSN: 0020-1669
A Sodium-Based Microporous Metal–Organic Framework Built on 2 Tetranuclear Clusters for Size-Dependent Sorting of Hexane Isomers
Jiafeng Miao, Muyang Zhou, Yuhan Wang, Jing Ling, Yilu Wu, Kang Zhou, Lian Pan, Manglai Gao, Hao WangAbstract
The construction of alkali metal-based metal–organic frameworks (AMOFs) with permanent porosity represents a notable challenge. Here we report a novel sodium-based MOF, designated HIAM-113, built on tetranuclear Na4 clusters and a tetracarboxylate linker. HIAM-113 features high structural robustness and one-dimensional channels that are optimal for size-sieving separation of hexane isomers.
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