A Review on Performance Optimization and Relevant Application Research of Heat Pump Technologies for Energy System Decarbonization

Heat pumps are core equipment for efficient low-grade thermal energy utilization and low-carbon transformation of the energy structure, offering significant energy-saving potential in building heating and industrial waste heat recovery. This paper reviews the research progress and technical challenges of compression, absorption, and adsorption heat pumps as well as nanofluid-enhanced heat transfer technology and elastocaloric heat pump systems. Air source heat pumps can delay frosting through variable frequency, heat storage, and waste heat recovery. However, accurate prediction models for performance degradation under extreme cold conditions are lacking. Although ground source and water source heat pumps exhibit significant energy efficiency advantages, ground source systems may suffer from performance degradation due to underground thermal imbalance. The application of water source systems is strictly constrained by water resource conditions. Driven by low-grade waste heat, absorption heat pumps employing traditional working pairs suffer from crystallization, corrosion, or high rectification energy consumption. The COP of a single-effect cycle under 80~100 °C waste heat is only 1.2~1.9, while hybrid cycles can reach approximately 3.2 at 120~150 °C. Although adsorption heat pumps achieve significantly improved performance under continuous heat recovery cycles, the full-scale power density of novel adsorbents such as metal–organic frameworks is inferior to the power density of traditional silica gel. Moreover, under off-design conditions, the performance drops by 23~48% compared to theoretical values. Nanofluids can enhance heat transfer, but the long-term effects of particle agglomeration at high temperatures on pump power consumption and system compatibility remain to be systematically evaluated. Elastocaloric heat pump systems can achieve refrigerant-free cooling, but current prototypes still cannot compete with traditional vapor compression systems in long-cycle fatigue reliability and power density. Current heat pump technologies generally face challenges such as insufficient adaptability to extreme conditions, bottlenecks in working fluids and materials, and a lack of long-term validation. Future research must construct a multi-source coupling optimization system, address common problems in working fluids and materials, promote long-term validation and kilowatt-level prototype demonstrations, and drive the large-scale deployment and engineering application of heat pump technology toward high efficiency, intelligence, and high reliability.