A Macro-Constitutive Damage Modelling Framework for Biomass-Modified Cement Mortars Under Compressive Loading: Experimental Calibration and Sustainability Assessment

The integration of bio-based constituents into cementitious materials requires robust predictive models capable of describing mechanical degradation while supporting sustainability-driven material design. This study presents a macro-constitutive damage modelling framework for biomass-modified cement mortars subjected to monotonic compressive loading, combining experimental characterisation, continuum damage mechanics (CDM), and life-cycle assessment (LCA). The calibrated parameters are interpreted in terms of meso-scale mechanisms, but the study does not constitute a direct imaging-based multiscale characterisation. Mortars containing 0–10% dried microalgal biomass as a partial replacement for binder mass were investigated through their complete compressive stress–strain response. A scalar damage variable was employed to model stiffness degradation and progressive microcrack evolution, enabling the identification of elastic-modulus reduction, damage-initiation thresholds, softening behaviour, and residual load-bearing capacity. A thermodynamically consistent Mazars-type damage model was calibrated against the measured envelopes and internally verified by reproducing the same pre-peak and post-peak responses, with coefficients of determination ranging from 0.979 to 0.996. Increasing biomass content reduced the 28-day compressive strength from 47.8 to 23.7 MPa and the elastic modulus from 27.5 to 14.9 GPa, while increasing the damage level at peak load from 0.26 to 0.46 and promoting a more gradual post-peak softening response. The calibrated law provides a compact constitutive representation within the tested replacement range; independent external validation is still required before extrapolation to other biomass types, mixture proportions, or curing regimes. In parallel, a cradle-to-gate LCA quantified global warming, acidification, eutrophication, ozone depletion, and abiotic depletion potentials. An integrated carbon-efficiency index was used to relate mechanical performance to environmental impact. Biomass replacement reduced global warming potential by up to 7.7% but increased eutrophication potential, highlighting a clear performance–environment trade-off. Despite the reduction in mechanical properties, all mixtures satisfied masonry-unit strength requirements, supporting the application of biomass-modified mortars in low-carbon concrete masonry units. The proposed framework demonstrates how experimentally calibrated damage models can support the structural assessment and sustainable development of emerging bio-based cementitious materials.