DOI: 10.1039/d3sc02292g ISSN: 2041-6520

A dinuclear Rh(−i)/Rh(i) complex bridged by biphilic phosphinine ligands

Koichiro Masada, Kiyosumi Okabe, Shuhei Kusumoto, Kyoko Nozaki
  • General Chemistry

A dinuclear Rh(−

i
)/Rh(
i
) complex bridged by tridentate phosphinine ligands was prepared by reduction of the corresponding Rh(
i
) complex. An unsymmetric bridging mode of the phosphinine differentiated the electronic environments of the Rh centres.

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