DOI: 10.1039/d3sc02292g ISSN: 2041-6520
A dinuclear Rh(−i )/Rh(i ) complex bridged by biphilic phosphinine ligands
Koichiro Masada, Kiyosumi Okabe, Shuhei Kusumoto, Kyoko Nozaki - General Chemistry
A dinuclear Rh(−
i
)/Rh(i
) complex bridged by tridentate phosphinine ligands was prepared by reduction of the corresponding Rh(i
) complex. An unsymmetric bridging mode of the phosphinine differentiated the electronic environments of the Rh centres.