A Designable Edge–Contact Architecture for Probing Edge Effects in Structural Superlubric Graphite Interfaces

Structural superlubricity enables ultralow friction and wear–free sliding by cancellation of lateral forces at incommensurate, weakly interacting interfaces. However, edge–induced friction remains non–negligible. In this work, we systematically quantify edge–induced friction in atomically smooth single–crystal graphite/graphite interfaces using a controlled edge–contact architecture. By introducing holes with well–defined geometries and sizes, we systematically vary the total contact edge length while preserving the crystallinity and atomically smooth morphology of the interior graphite surface. The results reveal that friction enhancement in the patterned graphite/graphite interface is dominated by edge–mediated interactions at the hole boundary, demonstrating that total edge length, rather than real contact area, is the primary parameter governing interfacial friction. This outcome diverges from conventional contact–area–dependent friction theories, bringing to light the paramount importance of edge contributions in structurally superlubric interfaces. We show that engineering the hole perimeter provides a route to tuning friction in layered materials without changing material composition or external operating conditions.