DOI: 10.1039/d6ra04050k ISSN: 2046-2069

A closer look into transfer hydrogenation between perhydro-dibenzyltoluene (H 18 -DBT) and acetone for safe hydrogen release using Pt-based catalysts

Smitkriti, Xiaolong Ji, Laurent Veyre, Antoinette Boréave, Zhigang Yan, Isabelle Pitault, Clément Camp, Valérie Meille, Chloé Thieuleux

Transfer hydrogenation between H 18 -DBT and acetone was reinvestigated, studying the reaction products, the effect of Pt nanoparticle size, support and metal loadings. Water addition was found to prevent the major side-reaction and catalyst poisoning.

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