DOI: 10.1039/d3sc03342b ISSN:
Kinetics of ligand exchange in solution: a quantitative mass spectrometry approach
Quentin Duez, Paul Tinnemans, Johannes A. A. W. Elemans, Jana Roithová- General Chemistry
Delayed reactant labelling can provide thermodynamic parameters (ΔG, ΔH, and ΔS) of solution equilibria using ESI-MS monitoring. As a proof of concept, we investigated the equilibria of pyridine ligands with macrocyclic porphyrin cage complexes.