Bis(neopentylglycolato)diboron (B2nep2) as a bidentate ligand and a reducing agent for early transition metal chlorides giving MCl4(B2nep2) complexes

doi:10.1039/d3dt01828h

DOI: 10.1039/d3dt01828h ISSN:

Bis(neopentylglycolato)diboron (B₂nep₂) as a bidentate ligand and a reducing agent for early transition metal chlorides giving MCl₄(B₂nep₂) complexes

Hiromu Hosoya, Takuya Akiyama, Kazushi Mashima, Hayato Tsurugi

Inorganic Chemistry

We found that bis(neopentylglycolato)diboron (B₂nep₂) served as a bidentate ligand and a one-electron reducing agent for early transition metal chlorides to afford MCl₄(B₂nep₂).

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