DOI: 10.1039/d3ra07120k ISSN: 2046-2069

Anderson-type polyoxometalate-based metal–organic framework as an efficient heterogeneous catalyst for selective oxidation of benzylic C–H bonds

Hong-Ru Tan, Xiang Zhou, Tengfei Gong, Hanqi You, Qi Zheng, Sheng-Yin Zhao, Weimin Xuan
  • General Chemical Engineering
  • General Chemistry

Self-assembly of Anderson-type polyoxometalate {CrMo6} with Cu2+ and bistriazole L affords POMOF-1 that works cooperatively with NPHI for oxidative transformation of benzylic C–H bonds into carbonyl compounds.

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